(4-Methylbenzohydrazidato-κ2 N′,O)[2-(4-methylbenzoylhydrazinylidene-κ2 N,O)-3-phenylpropionato(2−)]oxidovanadium(V) methanol monosolvate
نویسندگان
چکیده
The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazono)propionate dianion. The octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds, generating a centrosymmetric aggregate.
منابع مشابه
(4-Chlorobenzohydrazidato-κ2 N′,O)[2-(4-chlorobenzoylhydrazinylidene-κ2 N 1,O)-3-phenylpropionato(2−)-κO 1]oxidovanadium(V) methanol monosolvate
The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazinyl-idene)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds ab...
متن کاملBis(μ-methanolato-κ2 O:O)bis{[4-bromo-N′-(1-methyl-3-oxidobut-2-en-1-ylidene-κO)benzohydrazidato-κ2 N′,O]oxidovanadium(V)}
The dinuclear compound, [V(2)(C(12)H(11)BrN(2)O(2))(2)(CH(3)O)(2)O(2)], lies on a center of inversion. The doubly-deprotonated Schiff base O,N,O'-chelates to the V(V) atom; two metal atoms are bridged by the methoxide units. The coordination geometry is a distorted octa-hedron. Weak inter-molecular C-H⋯N hydrogen bonding is present in the crystal structure. The bromo-phenyl unit is disordered o...
متن کامل(Benzohydrazidato-κ2 N′,O)[2-(benzoylhydrazono-κ2 N,O)propionato-κO]oxidovanadium(V)
The V(V) atom in the title compound, [VO(C(7)H(7)N(2)O)(C(10)H(8)N(2)O(3))], is N,O-chelated by the benzohydrazidate anion and O,N,O'-chelated by the 2-(benzoyl-hydrazono)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vandadyl O atom. Mol-ecules are linked by N-H⋯O hydrogen bonds into a supra-molecular chain structure parallel to [010].
متن کامل[N′-(3,5-Diiodo-2-oxidobenzylidene-κO)-4-methylbenzohydrazidato-κ2 N′,O](methanol-κO)(methanolato-κO)oxidovanadium(V)
In the title mol-ecule, [V(C(15)H(10)I(2)N(2)O(2))(CH(3)O)O(CH(3)OH)], the V(V) atom is coordinated by one N and two O atoms from an N'-(3,5-diiodo-2-oxidobenzyl-idene-κO)-4-methyl-benzo-hydra-zidate (L) ligand, one oxide O atom, one methano-late [V-O = 1.761 (3) Å] and one methanol [V-O = 2.383 (4) Å] O atom in a distorted octa-hedral geometry. In the L ligand, the two benzene rings are nearly...
متن کامل[N′-(3-Ethoxy-2-oxidobenzylidene-κO 2)-4-methylbenzohydrazidato-κ2 O,N′](methanolato-κO)oxidovanadium(V)
The title oxidovanadium(V) complex, [V(C(17)H(16)N(2)O(3))(CH(3)O)O], was obtained by the reaction of 3-eth-oxy-2-hy-droxy-benzaldehyde, 4-methyl-benzohydrazide and vanadyl sulfate in methanol. The V(V) atom is coordinated by the O,N,O'-tridentate Schiff base ligand, one methano-late O atom and one oxide O atom, forming a distorted VO(4)N square-pyramidal coordination geometry. The oxide O atom...
متن کامل