(4-Methyl­benzohydrazidato-κ2 N′,O)[2-(4-methyl­benzoyl­hydrazinyl­idene-κ2 N,O)-3-phenyl­propionato(2−)]oxido­vanadium(V) methanol monosolvate

نویسندگان

  • Hon Wee Wong
  • Kong Mun Lo
  • Seik Weng Ng
چکیده

The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazono)propionate dianion. The octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent mol-ecules are linked by O-H⋯O and O-H⋯N hydrogen bonds, generating a centrosymmetric aggregate.

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(4-Chloro­benzohydrazidato-κ2 N′,O)[2-(4-chloro­benzoyl­hydrazinyl­idene-κ2 N 1,O)-3-phenyl­propionato(2−)-κO 1]oxidovanadium(V) methanol monosolvate

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[N′-(3,5-Diiodo-2-oxidobenzyl­idene-κO)-4-methyl­benzohydrazidato-κ2 N′,O](methanol-κO)(methano­lato-κO)oxidovanadium(V)

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010